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Accessibility information
Author(s):   Ma, A.; Sun, L-P.; Wang, Y-X.; Liu, C-B.; Deng, C-H.
Title:   A theoretical study of the decompositions of CF3CO and CF3C(O) radicals
Journal:   Gaodeng Xuexiao Huaxue Xuebao
Volume:   17
Page(s):   777 - 780
Year:   1996
Reference type:   Journal article
Squib:   1996MA/SUN777-780

Reaction:   CF3C(O)O → CO2 + ·CF3
Reaction order:   1
Temperature:   100 - 1500 K
Rate expression:   3.89x1013 [s-1] e-20204 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
100 1.09E3
200 2.06E8
300 1.18E10
400 8.95E10
500 3.01E11
600 6.78E11
700 1.21E12
800 1.87E12
900 2.61E12
1000 3.42E12
1100 4.27E12
1200 5.13E12
1300 6.00E12
1400 6.86E12
1500 7.70E12