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Title: Hydrogen atom attack on fluorotoluenes: Rates of fluorine displacement
Journal: Isr. J. Chem.
Volume: 36
Page(s): 263 - 273
Year: 1996
Reference type: Journal article
Squib: 1996MAN/TSA263-273
Reaction:
2-Fluorotoluene + H· → Toluene + ·F
Reaction order:
2
Reference reaction:
1,3,5-Trimethylbenzene + H· → 1,3-Dimethylbenzene + ·CH3
Reference reaction order:
2
Temperature:
1012 - 1142
K
Pressure: 2.00 - 2.50 bar
Rate expression:
1.25±2.9x10-1 e-10061 [±807 J/mole]/RT
Uncertainty:
1.4
Bath gas:
Ar
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
None reported
Experimental procedure:
Shock tube
Excitation technique:
Thermal
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 1012 | 3.78E-1 |
| 1025 | 3.84E-1 |
| 1050 | 3.95E-1 |
| 1075 | 4.06E-1 |
| 1100 | 4.16E-1 |
| 1125 | 4.26E-1 |
| 1142 | 4.33E-1 |