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Accessibility information
Author(s):   Manion, J.A.; Tsang, W.
Title:   Hydrogen atom attack on fluorotoluenes: Rates of fluorine displacement
Journal:   Isr. J. Chem.
Volume:   36
Page(s):   263 - 273
Year:   1996
Reference type:   Journal article
Squib:   1996MAN/TSA263-273

Reaction:   3-Fluorotoluene + Toluene + ·F
Reaction order:   2
Reference reaction:   1,3,5-Trimethylbenzene + 1,3-Dimethylbenzene + ·CH3
Reference reaction order:   2
Temperature:   1012 - 1142 K
Pressure:  2.00 - 2.50 bar
Rate expression:   1.99±1.55 e-12838 [±2228 J/mole]/RT
Uncertainty:   1.4
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
1012 4.33E-1
1025 4.41E-1
1050 4.57E-1
1075 4.73E-1
1100 4.89E-1
1125 5.04E-1
1142 5.15E-1