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Accessibility information
Author(s):   Manion, J.A.; Tsang, W.
Title:   Hydrogen atom attach on 1,2-dichlorotetrafluoroethane: rates of halogen abstraction
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   7060 - 7065
Year:   1996
Reference type:   Journal article
Squib:   1996MAN/TSA7060-7065

Reaction:   1,3,5-Trimethylbenzene + 1,3-Dimethylbenzene + ·CH3
Reaction order:   2
Reference reaction:   CF2Cl-CF2Cl + → ·CF2CF2Cl + HCl
Reference reaction order:   2
Temperature:   970 - 1140 K
Rate expression:   3.2x10-1±1.1x10-1 e21451 [±2794 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
970 4.57E0
975 4.51E0
1000 4.22E0
1025 3.97E0
1050 3.73E0
1075 3.53E0
1100 3.34E0
1125 3.17E0
1140 3.08E0