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Title: Pulsed laser powered homogeneous pyrolysis for reaction kinetics studies: probe laser measurement of reaction time and temperature
Journal: Int. J. Chem. Kinet.
Volume: 28
Page(s): 817 - 828
Year: 1996
Reference type: Journal article
Squib: 1996SWI/CAR817-828
Reaction:
CH3COOC2H5 → CH3C(O)OH + C2H4
Reaction order:
1
Temperature:
960 - 1160
K
Pressure: 0.13 bar
Rate expression:
1.0x1012 [s-1] e-199547 [±17959 J/mole]/RT
Uncertainty:
10.0
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
Comments:
Experiments were carried out with the pulsed laser powered homogeneous pyrolysis technique.
The authors do not report the exact temperature range of their experiments. The stated temperature range was derived from the data shown in Figure 7 of the paper and is approximate.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 960 | 1.39E1 |
| 975 | 2.04E1 |
| 1000 | 3.78E1 |
| 1025 | 6.78E1 |
| 1050 | 1.18E2 |
| 1075 | 2.01E2 |
| 1100 | 3.35E2 |
| 1125 | 5.43E2 |
| 1150 | 8.64E2 |
| 1160 | 1.03E3 |