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Author(s):   Tyndall, G.S.; Orlando, J.J.; Wallington, T.J.; Sehested, J.; Nielsen, O.J.
Title:   Kinetics of the reactions of acetonitrile with chlorine and fluorine atoms
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   660 - 668
Year:   1996
Reference type:   Journal article
Squib:   1996TYN/ORL660-668

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1996TYN/ORL660-668   CH3CN + ·F → Products  5.00 - 700   5.80E-11           5.80E-11  2
  1996TYN/ORL660-668   CH3CN + ·F → Products  296   2.90E-28              3
  1996TYN/ORL660-668   CH3CN + ·ClCH2CN + HCl  274 - 345   1.60E-11       1.78E04   1.22E-14  2
  1996TYN/ORL660-668   CH3CN + ·ClCH2CN + HCl  296   0.11              2
  Reference reaction:  CH4 + ·Cl·CH3 + HCl 2
  1996TYN/ORL660-668   CH2ClCN + ·Cl → Products  296   3.40E-14              2
  1996TYN/ORL660-668   CH2ClCN + ·Cl → Products  296   0.34              2
  Reference reaction:  CH4 + ·Cl·CH3 + HCl 2

Search returned 6 records.