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Accessibility information
Author(s):   Wurmel, J.; McGuinness, M.; Simmie, J.M.
Title:   High-temperature oxidation of ethylene oxide in shock waves
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   92
Page(s):   715 - 721
Year:   1996
Reference type:   Journal article
Squib:   1996WUR/MCG715-721

Reaction:   Oxirane·CH3 + HCO
Reaction order:   1
Temperature:   1050 - 1400 K
Rate expression:   3.63x1013 [s-1] e-239457 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 4.44E1
1075 8.41E1
1100 1.55E2
1125 2.77E2
1150 4.83E2
1175 8.22E2
1200 1.37E3
1225 2.24E3
1250 3.58E3
1275 5.62E3
1300 8.68E3
1325 1.32E4
1350 1.97E4
1375 2.91E4
1400 4.23E4