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Author(s):
Barry, J.; Locke, G.; Scollard, D.; Sidebottom, H.; Treacy, J.; Clerbaux, C.; Colin, R.; Franklin, J.
Title:
1,1,1,3,3,-pentafluorobutane (HFC-365mfc): atmospheric degradation and contribution to radiative forcing
Journal:
Int. J. Chem. Kinet.
Volume:
29
Page(s):
607 - 617
Year:
1997
Reference type:
Journal article
Squib:
1997BAR/LOC607-617
Reaction:
Propane, 1,1,1,3,3,3-hexafluoro- + Cl → HCl + (CF3)2CH·
Reaction order:
2
Reference reaction:
CF3CH2CF2CH3 + Cl → Other Products + HCl
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
1.0x10-17 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Time resolution:
In real time
Analytical technique:
Gas chromatography
View full bibliographic record.
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