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Title: Detailed kinetics of cyclopentadiene decomposition studied in a shock tube
Journal: Int. J. Chem. Kinet.
Volume: 29
Page(s): 505 - 514
Year: 1997
Reference type: Journal article
Squib: 1997BUR/DVI505-514
Reaction:
CH2=CHCH2CH2CH=CH2 → C2H4 + 1,3-Butadiene
Reaction order:
1
Temperature:
1080 - 1550
K
Pressure: 1.72 - 9.73 bar
Rate expression:
1.0x1012 [s-1] e-100605 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1080 | 1.36E7 |
| 1100 | 1.67E7 |
| 1125 | 2.13E7 |
| 1150 | 2.69E7 |
| 1175 | 3.37E7 |
| 1200 | 4.18E7 |
| 1225 | 5.13E7 |
| 1250 | 6.25E7 |
| 1275 | 7.56E7 |
| 1300 | 9.07E7 |
| 1325 | 1.08E8 |
| 1350 | 1.28E8 |
| 1375 | 1.51E8 |
| 1400 | 1.76E8 |
| 1425 | 2.05E8 |
| 1450 | 2.38E8 |
| 1475 | 2.74E8 |
| 1500 | 3.14E8 |
| 1525 | 3.58E8 |
| 1550 | 4.07E8 |