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Accessibility information
Author(s):   Burcat, A.; Dvinyaninov, M.
Title:   Detailed kinetics of cyclopentadiene decomposition studied in a shock tube
Journal:   Int. J. Chem. Kinet.
Volume:   29
Page(s):   505 - 514
Year:   1997
Reference type:   Journal article
Squib:   1997BUR/DVI505-514

Reaction:   CH2=CHCH2CH2CH=CH2C2H4 + 1,3-Butadiene
Reaction order:   1
Temperature:   1080 - 1550 K
Pressure:  1.72 - 9.73 bar
Rate expression:   1.0x1012 [s-1] e-100605 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1080 1.36E7
1100 1.67E7
1125 2.13E7
1150 2.69E7
1175 3.37E7
1200 4.18E7
1225 5.13E7
1250 6.25E7
1275 7.56E7
1300 9.07E7
1325 1.08E8
1350 1.28E8
1375 1.51E8
1400 1.76E8
1425 2.05E8
1450 2.38E8
1475 2.74E8
1500 3.14E8
1525 3.58E8
1550 4.07E8