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Title: Kinetics of the reaction between cyclopentylperoxy radicals and HO2
Journal: J. Phys. Chem. A
Volume: 101
Page(s): 5337 - 5343
Year: 1997
Reference type: Journal article
Squib: 1997CRA/SZE5337-5343
Reaction:
Cyclopentane + Cl → Cyclopentyl + HCl
Reaction order:
2
Reference reaction:
CH3OH + Cl → (·)CH2OH + HCl
Reference reaction order:
2
Temperature:
248 - 573
K
Rate expression:
2.3±3.0x10-1 e2494 [±1671 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 248 | 7.71E0 |
| 250 | 7.64E0 |
| 275 | 6.85E0 |
| 300 | 6.25E0 |
| 325 | 5.79E0 |
| 350 | 5.42E0 |
| 375 | 5.12E0 |
| 400 | 4.87E0 |
| 425 | 4.66E0 |
| 450 | 4.48E0 |
| 475 | 4.33E0 |
| 500 | 4.19E0 |
| 525 | 4.07E0 |
| 550 | 3.97E0 |
| 573 | 3.88E0 |