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Author(s):   DeMore, W.B.; Sander, S.P.; Golden, D.M.; Hampson, R.F.; Kurylo, M.J.; Howard, C.J.; Ravishankara, A.R.; Kolb, C.E.; Molina, M.J.
Title:   Chemical kinetics and photochemical data for use in stratospheric modeling. Evaluation number 12
Journal:   JPL Publication 97-4
Page(s):   1 - 266
Year:   1997
Reference type:   Journal article
Squib:   1997DEM/SAN1-266

Reaction:   CH3Br + ·OHH2O + ·CH2Br
Reaction order:   2
Temperature:   200 - 300 K
Rate expression:   4.0x10-12 [cm3/molecule s] e-12222 [±1222 J/mole]/RT
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
200 2.57E-15
225 5.82E-15
250 1.12E-14
275 1.91E-14
300 2.98E-14