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Author(s):   Kambanis, K.G.; Lazarou, Y.G.; Papagiannakopoulos, P.
Title:   Absolute rate constants for the reactions of Cl atoms with CH3Br, CH2Br2, and CHBr3
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   8496 - 8502
Year:   1997
Reference type:   Journal article
Squib:   1997KAM/LAZ8496-8502

Reaction:   CH3Br + ·ClHCl + ·CH2Br
Reaction order:   2
Temperature:   273 - 363 K
Rate expression:   1.66x10-11 [±1.33x10-12 cm3/molecule s] e-8896 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
273 3.30E-13
275 3.39E-13
300 4.69E-13
325 6.17E-13
350 7.81E-13
363 8.71E-13