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Author(s):   Kumaran, S.S.; Su, M.-C.; Lim, K.P.; Michael, J.V.; Klippenstein, S.J.; DiFelice, J.; Mudipalli, P.S.; Kiefer, J.H.; Dixon, D.A.; Peterson, K.A.
Title:   Experiments and theory on the thermal decomposition of CHCl3 and the reactions of CCl2
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   8653 - 8661
Year:   1997
Reference type:   Journal article
Squib:   1997KUM/SU8653-8661

Reaction:   CCl2 (X 1A1) + CCl2 (X 1A1)C2Cl4
Reaction order:   3
Temperature:   1280 - 1880 K
Pressure:  0.14 - 0.49 bar
Rate expression:   1.57x10-32 [cm6/molecule2 s] e24860 [J/mole]/RT
Bath gas:   Kr
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Laser schlieren

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
1280 1.63E-31
1300 1.57E-31
1350 1.44E-31
1400 1.33E-31
1450 1.24E-31
1500 1.15E-31
1550 1.08E-31
1600 1.02E-31
1650 9.62E-32
1700 9.12E-32
1750 8.68E-32
1800 8.28E-32
1850 7.91E-32
1880 7.71E-32