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Author(s):   Olsson, B.E.R.; Hallquist, M.; Ljungstrom, E.; Davidsson, I.
Title:   A kinetic study of chlorine radical reactions with ketones by laser photolysis technique
Journal:   Int. J. Chem. Kinet.
Volume:   29
Page(s):   195 - 201
Year:   1997
Reference type:   Journal article
Squib:   1997OLS/HAL195-201

Reaction:   (CH3)2CO + Cl → CH3C(O)CH2(·) + HCl
Reaction order:   2
Reference reaction:   ClONO2 + Cl → Cl2 + NO3
Temperature:   294 K
Pressure:  1.01 bar
Rate expression:   1.69x10-12 [±3.16x10-13 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

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