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Author(s):   Seetula, J.A.; Slagle, I.R.
Title:   Kinetics and thermochemistry of the R + HBr = RH + Br (R = n-C3H7, isoC3H7, n-C4H9, isoC4H9, sec-C4H9 or tert-C4H9)
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   93
Page(s):   1709 - 1719
Year:   1997
Reference type:   Journal article
Squib:   1997SEE/SLA1709-1719

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1997SEE/SLA1709-1719   tert-C4H9 + HBr → iso-C4H10 + Br·  301 - 667   1.20E-12       -8298      2
  1997SEE/SLA1709-1719   iso-C3H7 + HBr → C3H8 + Br·  304 - 667   1.40E-12       -6893      2
  1997SEE/SLA1709-1719   n-C3H7 + HBr → C3H8 + Br·  296 - 667   1.60E-12       -5396   1.41E-11  2
  1997SEE/SLA1709-1719   sec-C4H9 + HBr → n-C4H10 + Br·  302 - 610   1.40E-12       -7500      2
  1997SEE/SLA1709-1719   n-C4H9 + HBr → n-C4H10 + Br·  330 - 550   1.30E-12       -6394      2
  1997SEE/SLA1709-1719   iso-C4H9 + HBr → iso-C4H10 + Br·  301 - 550   1.40E-12       -6095      2
Search returned 6 records.