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Accessibility information
Author(s):   Berry, R.J.; Marshall, P.
Title:   A computational study of the reaction kinetics of methyl radicals with trifluorohalomethanes
Journal:   Int. J. Chem. Kinet.
Volume:   30
Page(s):   179 - 184
Year:   1998
Reference type:   Journal article
Squib:   1998BER/MAR179-184

Reaction:   CF3Br + ·CH3CH3Br + ·CF3
Reaction order:   2
Temperature:   298 - 2500 K
Rate expression:   5.43x10-14 [cm3/molecule s] (T/298 K)2.05 e-33175 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 8.32E-20
300 9.22E-20
400 4.62E-18
500 5.37E-17
600 2.95E-16
700 1.05E-15
800 2.81E-15
900 6.22E-15
1000 1.20E-14
1100 2.10E-14
1200 3.40E-14
1300 5.17E-14
1400 7.49E-14
1500 1.04E-13
1600 1.41E-13
1700 1.84E-13
1800 2.36E-13
1900 2.97E-13
2000 3.66E-13
2100 4.45E-13
2200 5.33E-13
2300 6.32E-13
2400 7.42E-13
2500 8.62E-13