NIST Chemical Kinetics Database

Author(s):   Czarnowski, J.
Title:   Kinetics and mechanism of the thermal gas-phase oxidation of tetrachloroethene by molecular oxygen in presence of trifluoromethylhypofluorite, CF₃OF
Journal:   Z. Phys. Chem. (Munich)
Volume:   203
Page(s):   183 - 197
Year:   1998
Reference type:   Journal article
Squib:   1998CZA183-197

Reaction:   C₂Cl₄ + CF₃OF → ·CCl₂CFCl₂ + CF₃O
Reaction order:   2
Temperature:   314 - 344 K
Pressure:  0.47 - 0.70 bar
Rate expression:   5.25x10^-14 [±1.16x10^-14 cm³/molecule s] e^{-63606 [±6992 J/mole]/RT}
Bath gas:   N2
Category: Theory
Data type:   Estimated: thermochemical, kinetic, or other

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [cm³/molecule s]
314	1.38E-24
325	3.14E-24
344	1.15E-23