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Author(s):   Fittschen, C.; Delcroix, B.; Gomez, N.; Devolder, P.
Title:   Rate constants for the reactions of CH3O with CH2O, CH3CHO and i-C4H10
Journal:   J. Chim. Phys.
Volume:   95
Page(s):   2129 - 2142
Year:   1998
Reference type:   Journal article
Squib:   1998FIT/DEL2129-2142

Reaction:   CH2O + CH3 → Other Products + CH3OH
Reaction order:   2
Temperature:   295 - 450 K
Pressure:  4.00E-3 - 0.50 bar
Rate expression:   1.1x10-12 [±2.99x10-13 cm3/molecule s] e-9562 [±956 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
295 2.23E-14
300 2.38E-14
325 3.19E-14
350 4.11E-14
375 5.12E-14
400 6.20E-14
425 7.34E-14
450 8.54E-14