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Accessibility information
Author(s):   Jodkowski, J.T.; Rayez, M-T.; Rayez, J-C.; Berces, T.; Dobe, S.
Title:   Theoretical study of the kinetics of the hydrogen abstraction from methanol. 1. Reaction of methanol with fluorine atoms
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   9219 - 9229
Year:   1998
Reference type:   Journal article
Squib:   1998JOD/RAY9219-9229

Reaction:   CH3OH + ·F(·)CH2OH + HF
Reaction order:   2
Temperature:   300 - 1000 K
Rate expression:   6.89x10-11 [cm3/molecule s] (T/298 K)0.27
Category:  Theory
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 6.90E-11
350 7.19E-11
400 7.46E-11
450 7.70E-11
500 7.92E-11
550 8.13E-11
600 8.32E-11
650 8.50E-11
700 8.67E-11
750 8.84E-11
800 8.99E-11
850 9.14E-11
900 9.28E-11
950 9.42E-11
1000 9.55E-11