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Author(s):   Jodkowski, J.T.; Rayez, M-T.; Rayez, J-C.; Berces, T.; Dobe, S.
Title:   Theoretical study of the kinetics of the hydrogen abstraction from methanol. 2. Reaction of methanol with chlorine and bromine atoms
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   9230 - 9243
Year:   1998
Reference type:   Journal article
Squib:   1998JOD/RAY9230-9243

Reaction:   CH3 + HClCH3OH + ·Cl
Reaction order:   2
Temperature:   300 - 1000 K
Rate expression:   2.66x10-14 [cm3/molecule s] (T/298 K)2.50 e-18541 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.60E-17
350 6.79E-17
400 2.10E-16
450 5.24E-16
500 1.12E-15
550 2.13E-15
600 3.71E-15
650 6.04E-15
700 9.28E-15
750 1.36E-14
800 1.93E-14
850 2.65E-14
900 3.53E-14
950 4.61E-14
1000 5.89E-14