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Accessibility information
Author(s):   Lifshitz, A.; Tamburu, C.
Title:   Thermal decomposition of acetonitrile. Kinetic modeling
Journal:   Int. J. Chem. Kinet.
Volume:   30
Page(s):   341 - 347
Year:   1998
Reference type:   Journal article
Squib:   1998LIF/TAM341-347

Reaction:   NCCH2CH2CNHCN + CH2CHCN
Reaction order:   1
Temperature:   1350 - 1950 K
Rate expression:   2.85x1013 [s-1] e-284512 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1350 2.80E2
1400 6.91E2
1450 1.61E3
1500 3.53E3
1550 7.36E3
1600 1.47E4
1650 2.81E4
1700 5.16E4
1750 9.18E4
1800 1.58E5
1850 2.64E5
1900 4.30E5
1950 6.82E5