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Accessibility information
Author(s):   Louis, F.; Sawerysyn, J.
Title:   Kinetics and products studies of reactions between fluorine atoms and CHF3, CHClF2, CHCl2F and CHCl3
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   94
Page(s):   1437 - 1445
Year:   1998
Reference type:   Journal article
Squib:   1998LOU/SAW1437-1445

Reaction:   CHCl3 + ·F·CCl3 + HF
Reaction order:   2
Temperature:   298 - 421 K
Pressure:  1.33E-3 - 4.00E-3 bar
Rate expression:   1.69x10-11 [±4.98x10-12 cm3/molecule s] e-4573 [±732 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.67E-12
300 2.71E-12
325 3.12E-12
350 3.52E-12
375 3.91E-12
400 4.28E-12
421 4.59E-12