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Author(s):   Pesa, M.; Pilling, M.J.; Robertson, S.H.; Wardlaw, D.M.
Title:   Application of the canonical flexible transition state theory to CH3, CF3, and CCl3
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   8526 - 8536
Year:   1998
Reference type:   Journal article
Squib:   1998PES/PIL8526-8536

Reaction:   ·CF3 + ·CF3C2F6
Reaction order:   2
Temperature:   300 - 2000 K
Rate expression:   8.39x10-12 [cm3/molecule s] (T/298 K)-0.79 e1169 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.33E-11
400 9.45E-12
500 7.38E-12
600 6.10E-12
700 5.22E-12
800 4.58E-12
900 4.10E-12
1000 3.71E-12
1100 3.40E-12
1200 3.14E-12
1300 2.92E-12
1400 2.73E-12
1500 2.57E-12
1600 2.43E-12
1700 2.30E-12
1800 2.19E-12
1900 2.09E-12
2000 2.00E-12