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Accessibility information
Author(s):   Seetula, J.A.
Title:   Kinetics of the R+Cl2, (R = CH2Cl, CHBrCl, CCl3 and CH3CCl2) reactions. An ab initio study of the transition states
Journal:   J. Chem. Soc. Farad. Trans.
Volume:   94
Page(s):   3561 - 3567
Year:   1998
Reference type:   Journal article
Squib:   1998SEE3561-3567

Reaction:   ·CH2Cl + Cl2CH2Cl2 + Cl
Reaction order:   2
Temperature:   295 - 873 K
Pressure:  5.82E11 - 5.93E11 bar
Rate expression:   2.93x10-13 [±5.03x10-15 cm3/molecule s] (T/298 K)1.45 e-350 [J/mole]/RT
Category:  Experiment
Data type:   Experimental value and limited review
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   GC-MS

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
295 2.50E-13
300 2.57E-13
350 3.27E-13
400 4.03E-13
450 4.84E-13
500 5.69E-13
550 6.59E-13
600 7.52E-13
650 8.49E-13
700 9.50E-13
750 1.05E-12
800 1.16E-12
850 1.27E-12
873 1.32E-12