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Author(s):   Sokolov, O.; Hurley, M.D.; Wallington, T.J.; Kaiser, E.W.; Platz, J.; Nielsen, O.J.; Berho, F.; Rayez, M.T.; Lesclaux, R.
Title:   Kinetics and mechanism of the gas-phase reaction of Cl atoms with benzene
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   10671 - 10681
Year:   1998
Reference type:   Journal article
Squib:   1998SOK/HUR10671-10681

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1998SOK/HUR10671-10681   Chlorobenzene + Cl → chlorophenyl radical (unspecified isomer) + HCl  296   <2.50E-16              2
  1998SOK/HUR10671-10681   Chlorobenzene + Cl → chlorophenyl radical (unspecified isomer) + HCl  296   0.02              2
  Reference reaction:  CHF2Cl + Cl → Products 2
  1998SOK/HUR10671-10681   6-chlorocyclohexadienyl radical + O2 → Products  296   <8.00E-17              2
  1998SOK/HUR10671-10681   Benzene + Cl → Phenyl + HCl  296   0.07              2
  Reference reaction:  CD4 + Cl → CD3 + DCl 2
  1998SOK/HUR10671-10681   Benzene + Cl → Phenyl + HCl  296   1.30E-16              2
  1998SOK/HUR10671-10681   Benzene + Cl → Phenyl + HCl  296   0.07              2
  Reference reaction:  CHF2Cl + Cl → Products 2
  1998SOK/HUR10671-10681   CHF2Cl + Cl → Products  296   1.70E-15              2
  1998SOK/HUR10671-10681   CHF2Cl + Cl → Products  296   0.28              2
  Reference reaction:  CD4 + Cl → CD3 + DCl 2
  1998SOK/HUR10671-10681   Benzene + Cl → Phenyl + HCl  296   4.20E-16              2
  1998SOK/HUR10671-10681   Benzene + Cl → 6-chlorocyclohexadienyl radical  296   1.00E-11              2
Search returned 10 records.