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Title: Rate constants and kinetic isotope effects in the reactions of atomic chlorine with n-butane and simple alkenes at room temperature
Journal: J. Phys. Chem. A
Volume: 102
Page(s): 8510 - 8519
Year: 1998
Reference type: Journal article
Squib: 1998STU/EZE8510-8519
Reaction:
1,3-Butadiene + Cl → Products
Reaction order:
2
Temperature:
293
K
Pressure: 1.33E-3 bar
Rate expression:
2.51x10-10 [±3.99x10-11 cm3/molecule s]
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Time resolution:
In real time
Analytical technique:
Resonance fluorescence
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