Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Vickier, C.; Vanhees, I.
Title:   Kinetic study in a microwave-induced plasma afterglow of the Cu (2S) atom reaction with CH3Br at temperatures between 300 and 804 K and with CH3I between 300 and 696 K
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   1349 - 1355
Year:   1998
Reference type:   Journal article
Squib:   1998VIC/VAN1349-1355

Reaction:   CH3Br + Cu·CH3 + CuBr
Reaction order:   2
Temperature:   300 - 804 K
Pressure:  1.20E-2 bar
Rate expression:   1.69x10-11 [±1.99x10-12 cm3/molecule s] e-8198 [±492 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 6.33E-13
350 1.01E-12
400 1.44E-12
450 1.89E-12
500 2.36E-12
550 2.82E-12
600 3.27E-12
650 3.72E-12
700 4.14E-12
750 4.55E-12
800 4.94E-12
804 4.97E-12