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Author(s):   Bierbach, A.; Barnes, I.; Becker, K.H.
Title:   Rate constants of the Br-initiated gas-phase oxidation of a series of alcohols, furans and benzenes at 300 ± 2 K
Journal:   Atmos. Environ.
Volume:   33
Page(s):   2981 - 2992
Year:   1999
Reference type:   Journal article
Squib:   1999BIE/BAR2981-2992

Reaction:   CH3OH + Br· → Other Products + Br·
Reaction order:   2
Reference reaction:   Cyclopentane + Br·Cyclopentyl + HBr
Temperature:   300 K
Pressure:  1.01 bar
Rate expression:   5.0x10-16 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography

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