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Title: The kinetics and mechanisms of gas phase elimination of primary, secondary, and tertiary 2-hydroxyalkylbenzenes
Journal: Int. J. Chem. Kinet.
Volume: 31
Page(s): 401 - 407
Year: 1999
Reference type: Journal article
Squib: 1999CHU/ROT401-407
Reaction:
2-Phenylethanol → CH2O + Toluene
Reaction order:
1
Temperature:
722 - 764
K
Rate expression:
9.3x1012 [s-1] e-249200 [J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Thermal
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
Reactor surface seasoned with allyl bromide.No effect of change in surface to volume by factor of 6.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 722 | 8.94E-6 |
| 725 | 1.03E-5 |
| 750 | 4.10E-5 |
| 764 | 8.42E-5 |