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Author(s):   Chuchani, G.; Rotinov, A.; Dominguez, R.M.
Title:   The kinetics and mechanisms of gas phase elimination of primary, secondary, and tertiary 2-hydroxyalkylbenzenes
Journal:   Int. J. Chem. Kinet.
Volume:   31
Page(s):   401 - 407
Year:   1999
Reference type:   Journal article
Squib:   1999CHU/ROT401-407

Reaction:   2-PhenylethanolCH2O + Toluene
Reaction order:   1
Temperature:   722 - 764 K
Rate expression:   9.3x1012 [s-1] e-249200 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Reactor surface seasoned with allyl bromide.No effect of change in surface to volume by factor of 6.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
722 8.94E-6
725 1.03E-5
750 4.10E-5
764 8.42E-5