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Accessibility information
Author(s):   DeMore, W.B.; Bayes, K.D.
Title:   Rate constants for the reactions of hydroxyl radical with several alkanes, cycloakanes, and dimethyl ether
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   2649 - 2654
Year:   1999
Reference type:   Journal article
Squib:   1999DEM/BAY2649-2654

Reaction:   n-C4H10 + ·OH → Other Products + H2O
Reaction order:   2
Reference reaction:   C2H6 + ·OH·C2H5 + H2O
Temperature:   235 - 361 K
Pressure:  1.01 bar
Rate expression:   1.68x10-11 [cm3/molecule s] e-4856 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
235 1.40E-12
250 1.62E-12
275 2.01E-12
300 2.39E-12
325 2.78E-12
350 3.16E-12
361 3.33E-12