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Title: A Flash-Photolysis/Laser Induced Fluorescence Spectroscopic Study of Rb(52S1/2) with CH3Cl and CFCl3 at Elevated Temperatures
Journal: J. Mol. Struct.
Volume: 482
Page(s): 277 - 281
Year: 1999
Reference type: Journal article
Squib: 1999MAR/ALB277-281
Reaction:
CF3Cl + Rb → ·CF3 + RbCl
Reaction order:
2
Temperature:
780 - 830
K
Rate expression:
1.6x10-12 [±5.0x10-1 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
This work was using LIF at 420.2nm, the rate constant is lower, cmpared to k=1.6e-11 (876K) measured by resonance absorption (1989HUS/JI1).
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