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Title: Kinetic Study of Gas-Phase Lu(2D3/2) with O2, N2O, and CO2
Journal: Chem. Phys. Lett.
Volume: 330
Page(s): 547 - 550
Year: 2000
Reference type: Journal article
Squib: 2000CAM547-550
Reaction:
CO2 + Lu → CO + LuO
Reaction order:
2
Temperature:
348 - 573
K
Pressure: 6.67E-3 bar
Rate expression:
2.0x10-10 [±6.0x10-11 cm3/molecule s] e-7600 [±1300 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
Lu from 248 nm photolysis of Lu(TMHD)3
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 348 | 1.45E-11 |
| 350 | 1.47E-11 |
| 375 | 1.75E-11 |
| 400 | 2.04E-11 |
| 425 | 2.33E-11 |
| 450 | 2.62E-11 |
| 475 | 2.92E-11 |
| 500 | 3.21E-11 |
| 525 | 3.51E-11 |
| 550 | 3.80E-11 |
| 573 | 4.06E-11 |