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Author(s):   Christensen, L.K.; Ball, J.C.; Wallington, T.J.
Title:   Atmospheric Oxidation Mechanism of Methyl Acetate
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   345 - 351
Year:   2000
Reference type:   Journal article
Squib:   2000CHR/BAL345-351

Reaction:   (CH3)2CO + Cl → Products
Reaction order:   2
Reference reaction:   CH3Cl + Cl → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   4.69±1.6x10-1
Bath gas:   Air
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Photolysis of Cl2 in 700 Torr O2/N2 as a source of Cl atoms in a 140 L Pyrex reactor coupled with FTIR spectrometer at T= 296 ?2 K.

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