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Title: Atmospheric Oxidation Mechanism of Methyl Acetate
Journal: J. Phys. Chem. A
Volume: 104
Page(s): 345 - 351
Year: 2000
Reference type: Journal article
Squib: 2000CHR/BAL345-351
Reaction:
(CH3)2CO + Cl → Products
Reaction order:
2
Temperature:
296
K
Pressure: 0.93 bar
Rate expression:
2.2x10-12 [±4.0x10-13 cm3/molecule s]
Bath gas:
Air
Category: Experiment
Data type:
Relative value normalized by a reference value
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
In real time
Analytical technique:
Fourier transform (FTIR)
Comments:
The reported rate constant is an average of four relative determinations with C2H5F, CH3Cl, CH3F and C2H5Cl as references. Authors state the error limits include 10% uncertainty in the rate constants of reference reactions.Photolysis of Cl2 in 700 Torr O2/N2 as a source of Cl atoms in a 140 L Pyrex reactor coupled with FTIR spectrometer at T= 296 ?2 K.
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