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Title: An Experimental Method for Testing Reactivity Models: A High-Pressure Discharge-Flow Study of H + Alkene and Haloalkene Reactions
Journal: J. Phys. Chem. A
Volume: 104
Page(s): 5254 - 5264
Year: 2000
Reference type: Journal article
Squib: 2000CLA/DON5254-5264
Reaction:
C2Cl4 + H· → Products
Reaction order:
2
Temperature:
298 - 370
K
Pressure: 6.67E-2 bar
Rate expression:
8.75x10-12 [±1.33x10-12 cm3/molecule s] e-16055 [±391 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Time resolution:
In real time
Analytical technique:
Resonance fluorescence
Comments:
Authors did not provide fits of the temperature dependence in the standard Arrhenius form. The listed values were calculated at NIST from the data in Table 2 of the paper.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 1.34E-14 |
| 300 | 1.40E-14 |
| 325 | 2.30E-14 |
| 350 | 3.52E-14 |
| 370 | 4.74E-14 |