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Title: Kinetics of Pb reactions with N2O, Cl2, HCl, and O2 at high temperatures
Journal: J. Phys. Chem. A
Volume: 104
Page(s): 5517 - 5524
Year: 2000
Reference type: Journal article
Squib: 2000COS/FON5517-5524
Reaction:
Pb + N2O → PbO + N2
Reaction order:
2
Temperature:
650 - 1205
K
Pressure: 1.00E-2 - 0.15 bar
Rate expression:
1.8x10-10 [±6.0x10-11 cm3/molecule s] e-74398 [J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 650 | 1.89E-16 |
| 700 | 5.06E-16 |
| 750 | 1.19E-15 |
| 800 | 2.50E-15 |
| 850 | 4.82E-15 |
| 900 | 8.66E-15 |
| 950 | 1.46E-14 |
| 1000 | 2.34E-14 |
| 1050 | 3.58E-14 |
| 1100 | 5.28E-14 |
| 1150 | 7.52E-14 |
| 1200 | 1.04E-13 |
| 1205 | 1.07E-13 |