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Author(s):   Goos, E.; Hippler, H.; Hoyermann, K.; Jurges, B.
Title:   Laser Powered Homogeneous Pyrolysis of Butane Initiated by Methyl Radicals in a Quasi-Wall-Free Reactor at 750-1000 K
Journal:   Phys. Chem. Chem. Phys.
Page(s):   5127 - 5132
Year:   2000
Reference type:   Journal article
Squib:   2000GOO/HIP5127-5132

Reaction:   n-C4H10 + ·CH3 → Products
Reaction order:   2
Temperature:   1000 K
Pressure:  8.00E-2 - 0.13 bar
Rate expression:   1.33x10-14 [cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In both real time and by end product analysis
Analytical technique:   GC-MS
Comments:   The product distribution and the temperature dependence were analyzed by a kinetic model of 61 species and 164 reactions developed for the high-temperature butane and the low-temperature n-pentane oxidation

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