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Title: Laser Powered Homogeneous Pyrolysis of Butane Initiated by Methyl Radicals in a Quasi-Wall-Free Reactor at 750-1000 K
Journal: Phys. Chem. Chem. Phys.
Page(s): 5127 - 5132
Year: 2000
Reference type: Journal article
Squib: 2000GOO/HIP5127-5132
Reaction:
n-C4H10 + ·CH3 → Products
Reaction order:
2
Temperature:
1000
K
Pressure: 8.00E-2 - 0.13 bar
Rate expression:
1.33x10-14 [cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In both real time and by end product analysis
Analytical technique:
GC-MS
Comments:
The product distribution and the temperature dependence were analyzed by a kinetic model of 61 species and 164 reactions developed for the high-temperature butane and the low-temperature n-pentane oxidation
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