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Title: Reaction Rate Constant for Ar(3P2) Metastable Atoms with the Tetramethylsilane Molecule
Journal: Chem. Phys. Lett.
Volume: 327
Page(s): 351 - 358
Year: 2000
Reference type: Journal article
Squib: 2000JAU/JAU351-358
Reaction:
Ar(3P_2) + (CH3)4Si → (CH3)2Si + Ar
Reaction order:
2
Reference reaction:
Ar(3P_2) + (CH3)4Si → Products
Reference reaction order:
2
Temperature:
298
K
Rate expression:
1.5x10-1
Bath gas:
Ar(^3P_2)
Category: Experiment
Data type:
Relative rate value measured
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Time resolution:
In real time
Analytical technique:
Mass spectrometry
Comments:
Overall rate constant reported as in the range 6 x 10-18 to 2.2 x 10-17 cm3 s-1. Ar(3P2) mesured by absorption spectroscopy.
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