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Title: Rate Constants for the Reactions of Cl Atoms with HCOOH and with HOCO Radicals
Journal: Int J. Chem. Kinet.
Volume: 32
Page(s): 85 - 91
Year: 2000
Reference type: Journal article
Squib: 2000LI/OSB85-91
Reaction:
HOCO + Cl → CO2 + HCl
Reaction order:
2
Temperature:
298
K
Pressure: 1.33E-2 bar
Rate expression:
4.8x10-11 [±1.0x10-11 cm3/molecule s]
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
IR absorption
Comments:
Reference indicates that the measurements were conducted at "room temperature". For the purposes of this data base is T=298 K is assumed.
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