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Title: Shock-tube and modeling study of acetone pyrolysis and oxidation
Journal: Combust. Flame
Volume: 122
Page(s): 291 - 311
Year: 2000
Reference type: Journal article
Squib: 2000SAT/HID291-311
Reaction:
(CH3)2CO + H· → H2 + CH3C(O)CH2(·)
Reaction order:
2
Temperature:
1050 - 1650
K
Pressure: 1.22 - 3.24 bar
Rate expression:
3.39x10-12 [cm3/molecule s] (T/298 K)2.00 e-20920 [J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Shock tube
Time resolution:
In real time
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 1050 | 3.83E-12 |
| 1100 | 4.69E-12 |
| 1150 | 5.66E-12 |
| 1200 | 6.76E-12 |
| 1250 | 7.97E-12 |
| 1300 | 9.32E-12 |
| 1350 | 1.08E-11 |
| 1400 | 1.24E-11 |
| 1450 | 1.42E-11 |
| 1500 | 1.61E-11 |
| 1550 | 1.81E-11 |
| 1600 | 2.03E-11 |
| 1650 | 2.26E-11 |