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Accessibility information
Author(s):   Sato, K.; Hidaka, Y.
Title:   Shock-tube and modeling study of acetone pyrolysis and oxidation
Journal:   Combust. Flame
Volume:   122
Page(s):   291 - 311
Year:   2000
Reference type:   Journal article
Squib:   2000SAT/HID291-311

Reaction:   (CH3)2CO + ·OHCH3C(O)CH2(·) + H2O
Reaction order:   2
Temperature:   1050 - 1650 K
Pressure:  1.22 - 3.24 bar
Rate expression:   3.32x10-11 [cm3/molecule s] e-12552 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   IR absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1050 7.89E-12
1100 8.42E-12
1150 8.94E-12
1200 9.44E-12
1250 9.93E-12
1300 1.04E-11
1350 1.09E-11
1400 1.13E-11
1450 1.17E-11
1500 1.21E-11
1550 1.25E-11
1600 1.29E-11
1650 1.33E-11