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Title: Kinetic and Modeling Studies of the Reaction of Hydroxyl Radicals with Tetrachloroethylene
Journal: J. Phys. Chem. A
Volume: 104
Page(s):
Year: 2000
Reference type: Journal article
Squib: 2000TIC/GRA12047
Reaction:
C2Cl4 + ·OH → Products
Reaction order:
2
Temperature:
296 - 720
K
Pressure: 0.99 bar
Rate expression:
1.6x10-14 [±1.65x10-15 cm3/molecule s] (T/298 K)3.20 e5494 [±454 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Vis-UV emission
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 296 | 1.46E-13 |
| 300 | 1.48E-13 |
| 325 | 1.61E-13 |
| 350 | 1.76E-13 |
| 375 | 1.94E-13 |
| 400 | 2.14E-13 |
| 425 | 2.35E-13 |
| 450 | 2.59E-13 |
| 475 | 2.85E-13 |
| 500 | 3.13E-13 |
| 525 | 3.44E-13 |
| 550 | 3.77E-13 |
| 575 | 4.13E-13 |
| 600 | 4.51E-13 |
| 625 | 4.92E-13 |
| 650 | 5.35E-13 |
| 675 | 5.81E-13 |
| 700 | 6.31E-13 |
| 720 | 6.72E-13 |