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Accessibility information
Author(s):   Tsang, W.; Mokrushin, V.
Title:   Mechanism and rate constants for 1,5-butadiene decomposition
Journal:   Proc. Combust. Inst.
Volume:   28
Page(s):   1717 - 1723
Year:   2000
Reference type:   Journal article
Squib:   2000TSA/MOK1717-1723

Reaction:   1,3-ButadieneCH2=C=CHCH3
Reaction order:   1
Temperature:   1200 - 1800 K
Pressure:  1.00 bar
Rate expression:   7.86x1031 [s-1] (T/298 K)-17.56 e-484484 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1200 1.53E0
1250 5.20E0
1300 1.57E1
1350 4.25E1
1400 1.05E2
1450 2.38E2
1500 5.00E2
1550 9.85E2
1600 1.83E3
1650 3.21E3
1700 5.37E3
1750 8.59E3
1800 1.32E4