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Title: Discharge Flow Reaction Kinetic Studies of O(3P) with Chloroethylenes CH2CCl2, CHClCCl2, CCl2CCl2
Journal: Chem. Phys. Lett.
Volume: 321
Page(s): 411 - 418
Year: 2000
Reference type: Journal article
Squib: 2000UPA/KUM411-418
Reaction:
CH2=CCl2 + O· → Products
Reaction order:
2
Temperature:
298
K
Pressure: 1.60E-3 - 2.00E-3 bar
Rate expression:
6.6x10-13 [±1.1x10-13 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Electron beam
Time resolution:
In real time
Analytical technique:
Chemiluminescence
Comments:
Room temperature measurementsCalculated Ea by PM3 3.5 kcal/mol; by CTAT 1.9 kcal/mol
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