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Author(s):   Upadhyaya, H.P.; Kumar, A.; Naik, P.D.; Sapre, A.V.
Title:   Discharge Flow Reaction Kinetic Studies of O(3P) with Chloroethylenes CH2CCl2, CHClCCl2, CCl2CCl2
Journal:   Chem. Phys. Lett.
Volume:   321
Page(s):   411 - 418
Year:   2000
Reference type:   Journal article
Squib:   2000UPA/KUM411-418

Reaction:   C2Cl4 + → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.60E-3 - 2.00E-3 bar
Rate expression:   1.9x10-13 [±3.0x10-14 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Chemiluminescence
Comments:   Room temperature measurementsCalculated Ea by PM3 5.3 kcal/mol; by CTST 2.5 kcal/mol

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