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Accessibility information
Author(s):   Bryukov, M.G.; Slagle, I.R.; Knyazev, V.D.
Title:   Kinetics of Reactions of H Atoms with Methane and Chlorinated Methanes
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   3107 - 3122
Year:   2001
Reference type:   Journal article
Squib:   2001BRY/SLA3107-3122

Reaction:   CCl4 + ·CCl3 + HCl
Reaction order:   2
Temperature:   297 - 904 K
Pressure:  3.80E-3 - 8.84E-3 bar
Rate expression:   1.36x10-10 [±3.1x10-11 cm3/molecule s] e-24420 [±765 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Analytical technique:   Resonance fluorescence
Comments:   Error limits are 2sigma and reflect only statistical contributions.


View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
297 6.90E-15
300 7.62E-15
350 3.08E-14
400 8.81E-14
450 1.99E-13
500 3.82E-13
550 6.52E-13
600 1.02E-12
650 1.48E-12
700 2.05E-12
750 2.71E-12
800 3.46E-12
850 4.29E-12
900 5.20E-12
904 5.28E-12