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Accessibility information
Author(s):   Bryukov, M.G.; Slagle, I.R.; Knyazev, V.D.
Title:   Kinetics of Reactions of H Atoms with Ethane and Chlorinated Ethanes
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   6900 - 6909
Year:   2001
Reference type:   Journal article
Squib:   2001BRY/SLA6900-6909

Reaction:   CH2ClCH2Cl + → Products
Reaction order:   2
Temperature:   483 - 826 K
Pressure:  2.44E-3 - 1.07E-2 bar
Rate expression:   1.45x10-10 [±4.8x10-11 cm3/molecule s] e-35669 [±1522 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Analytical technique:   Resonance fluorescence
Comments:   Error limits (2?igma? reflect only statistical contributions.


View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
483 2.01E-14
500 2.72E-14
525 4.10E-14
550 5.94E-14
575 8.34E-14
600 1.14E-13
625 1.51E-13
650 1.97E-13
675 2.52E-13
700 3.16E-13
725 3.90E-13
750 4.76E-13
775 5.72E-13
800 6.80E-13
825 8.00E-13
826 8.05E-13