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Home ©NIST, 2013 Accessibility information |
Title: Kinetics of Reactions of H Atoms with Ethane and Chlorinated Ethanes
Journal: J. Phys. Chem. A
Volume: 105
Page(s): 6900 - 6909
Year: 2001
Reference type: Journal article
Squib: 2001BRY/SLA6900-6909
Reaction:
CH3CCl3 + H· → Products
Reaction order:
2
Temperature:
358 - 850
K
Pressure: 2.44E-3 - 1.07E-2 bar
Rate expression:
1.83x10-10 [±6.2x10-11 cm3/molecule s] e-29533 [±1272 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Analytical technique:
Resonance fluorescence
Comments:
Error limits (2?igma? reflect only statistical contributions.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 358 | 8.98E-15 |
| 375 | 1.41E-14 |
| 400 | 2.55E-14 |
| 425 | 4.29E-14 |
| 450 | 6.83E-14 |
| 475 | 1.03E-13 |
| 500 | 1.50E-13 |
| 525 | 2.11E-13 |
| 550 | 2.87E-13 |
| 575 | 3.80E-13 |
| 600 | 4.91E-13 |
| 625 | 6.23E-13 |
| 650 | 7.75E-13 |
| 675 | 9.49E-13 |
| 700 | 1.14E-12 |
| 725 | 1.36E-12 |
| 750 | 1.61E-12 |
| 775 | 1.87E-12 |
| 800 | 2.16E-12 |
| 825 | 2.47E-12 |
| 850 | 2.80E-12 |