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Author(s):   Chuchani, G.; Rotinov, A.; Andres, J.; Domingo, L.r.; Safont, V.S.
Title:   A Combined Experimental and Theoretical Study of the Homogeneous, Reaction of HNO3 and NaCl(100)
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   1869 - 1875
Year:   2001
Reference type:   Journal article
Squib:   2001CHU/ROT1869-1875

Reaction:   CH2ClC(CH3)2COOHiso-C4H8 + CO2 + HCl
Reaction order:   1
Temperature:   654 - 703 K
Pressure:  5.73E-2 - 0.16 bar
Rate expression:   2.63x1012 [s-1] e-205800 [±4700 J/mole]/RT
Uncertainty:   2.29
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Other
Comments:   Concentrations were determined by HCl titration.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
654 9.43E-5
675 3.12E-4
700 1.16E-3
703 1.36E-3