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Title: Kinetic Study of OH and NO3 Radical Reactions with 14 Aliphatic Aldehydes
Journal: Phys. Chem. Chem. Phys.
Volume: 3
Page(s): 3057 - 3063
Year: 2001
Reference type: Journal article
Squib: 2001DAN/AND3057-3063
Reaction:
(CH3)2CHCHO + NO3 → Products
Reaction order:
2
Reference reaction:
1-C4H8 + NO3 → Products
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
1.26x10-14 [±1.4x10-15 cm3/molecule s]
Bath gas:
Air
Category: Experiment
Data type:
Relative rate value measured
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Thermal
Analytical technique:
Fourier transform (FTIR)
Comments:
NO3 from thermal dissociation of N2O5NO3 + But-1-ene taken as 1.35E-14 cm3/molec s
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